Effect of pore sizes on catalytic activities of arenetricarbonyl metal complexes constructed within Zr-based MOFs.
نویسندگان
چکیده
Arenetricarbonyl metal complexes ([-phM(CO)3-] and [-biphM(CO)3-]; ph = phenylene, biph = biphenylene, M = Mo, Cr) constructed within Zr-based MOFs act as highly active and selective catalysts for epoxidation of cyclooctene. Catalytic activities of these complexes are enhanced with increasing the pore sizes of Zr-based MOFs.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 42 26 شماره
صفحات -
تاریخ انتشار 2013